Methyl 2-{[(4-hydroxyphenyl)(methoxycarbonyl)methyl]aminocarbonyl}ethanoate hemihydrate
نویسندگان
چکیده
In the structure of the title compound, C(13)H(15)NO(6)·0.5H(2)O, the water O atom lies on a twofold rotation axis. The methoxy-carbonyl-methyl and amino groups are essentially coplanar and the methoxy-carbonyl-methyl group makes a dihedral angle of 79.73 (10)° with the mean plane of the hydroxy-phenyl ring. The amino and methoxy-carbonyl-methyl groups are involved in an intra-molecular N-H⋯O hydrogen bond which generates an S(5) ring motif. In the crystal structure, mol-ecules are linked via N-H⋯O and O-H⋯O hydrogen bonds and weak C-H⋯O inter-actions into a two-dimensional network parallel to the (01) plane. The crystal structure is further stabilized by C-H⋯π inter-actions.
منابع مشابه
[4-(Methoxycarbonyl)benzyl]triphenylphosphonium bromide hemihydrate
In the crystal structure of the title compound, C(27)H(24)O(2)P(+)·Br(-)·0.5H(2)O, there are inter-molecular O-H⋯Br hydrogen bonds between the H atoms of the water of crystallization and the bromide anions. The three phenyl rings of the triphenyl-phosphonium moiety are at angles of 59.73 (15), 79.15 (14) and 82.81 (17)° with the C/P/C planes.
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